Iodido(1,10-phenanthroline-κ2 N,N′)(piperine-1-carbodithioato-κ2 S,S′)copper(II)
نویسنده
چکیده
In the title compound, [Cu(C(6)H(10)NS(2))I(C(12)H(8)N(2))], the Cu(II) ion is coordinated by one iodide ion, two N atoms of the phenanthroline ligand and two S atoms from the piperidyl-dithio-carbamate ligand in a distorted square-pyramidal environment.
منابع مشابه
(N,N-Diethyldithiocarbamato-κ2 S,S′)iodido(1,10-phenanthroline-κ2 N,N′)copper(II)
The copper(II) atom in the title compound, [Cu(C(5)H(10)NS(2))I(C(12)H(8)N(2))], is chelated by the N-heterocycle and the dithio-carbamate anion in a slightly distorted tetragonal coordination. The tetragonal-pyramidal coorination is completed by the iodine atom in the apical position. One ethyl group is disordered over two positions with site occupancies of 0.31 (2) and 0.69 (2).
متن کاملA second polymorph of catena-poly[[(1,10-phenanthroline-κ2 N,N′)copper(II)]-di-μ-thiocyanato-κ2 N:S;κ2 S:N]
In the title coordination polymer, [Cu(NCS)(2)(C(12)H(8)N(2))](n), the Cu(II) atom is situated on a twofold rotation axis and is coordinated by two N atoms from the bidentate 1,10-phenanthroline ligand and four thio-cyanate groups to confer a CuN(4)S(2) octa-hedral geometry and resulting in a layer structure extending parallel to (100).
متن کاملcatena-Poly[[(1,10-phenanthroline-κ2 N,N′)copper(I)]-μ2-iodido]
The solvothermal reaction of copper(I) iodide and 1,10-phenanthroline (phen) in ethanol yielded the title polymeric compound, [CuI(C(12)H(8)N(2))](n). The asymmmetric unit comprises one Cu(+) cation, one I(-) anion and one phen ligand. Each Cu(+) cation is in a distorted tetrahedral coordination by two iodide anions and two N atoms from a bidentate chelating phen ligand. The Cu(+) cations are b...
متن کاملcatena-Poly[[(1,10-phenanthroline-κ2 N,N′)copper(I)]-μ-thiocyanato-κ2 N:S-[(1,10-phenanthroline-κ2 N,N′)copper(I)]-μ-cyanido-κ2 N:C]
In the title complex, [Cu(2)(CN)(NCS)(C(12)H(8)N(2))(2)], which was synthesized under hydro-thermal conditions, both Cu(I) atoms have a slightly distorted tetra-hedral geometry. They are coordinated by two N atoms of one 1,10-phenanthroline ligand, one bridging thio-cyanate anion and one bridging cyanide anion. In the crystal structure, infinite helical {Cu-CN-Cu-SCN}(n) chains are formed along...
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In the title complex, [Cu(C(12)H(13)NO(5))(C(12)H(8)N(2))]·0.5H(2)O, the Cu(II) ion is five-coordinated by one N atom and two O atoms from a tridentate Schiff base ligand, derived from the condensation of l-threonine and o-vanillin, and two N atoms from a 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. In the crystal, inter-molecular O-H⋯O hydrogen bonds form a one-dimensio...
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